ASTM D4629 Standard Test Method for Trace Nitrogen in Liquid Petroleum Hydrocarbons by Syringe/Inlet Oxidative Combustion and Chemiluminescence Detection
ASTM D4629注射/插入氧化燃料和化學(xué)發(fā)光法測定液態(tài)石油碳?xì)浠衔镏泻哿坑袡C結(jié)合物氮的標(biāo)準(zhǔn)試驗方法
Some process catalysts used in petroleum and chemical refining may be poisoned when even trace amounts of nitrogenous materials are contained in the feedstocks. This test method can be used to determine bound nitrogen in process feeds and may also be used to control nitrogen compounds in finished products.
1. Scope
1.1 This test method covers the determination of the trace total nitrogen naturally found in liquid hydrocarbons boiling in the range from approximately 50 to 400°C, with viscosities between approximately 0.2 and 10 cSt (mm2/s) at room temperature. This test method is applicable to naphthas, distillates, and oils containing 0.3 to 100 mg/kg total nitrogen. For liquid hydrocarbons containing more than 100 mg/kg total nitrogen, Test Method D5762 can be more appropriate. This test method has been successfully applied, during interlaboratory studies, to sample types outside the range of the scope by dilution of the sample in an appropriate solvent to bring the total nitrogen concentration and viscosity to within the range covered by the test method. However, it is the responsibility of the analyst to verify the solubility of the sample in the solvent and that direct introduction of the diluted sample by syringe into the furnace does not cause low results due to pyrolysis of the sample or solvent in the syringe needle.
1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.
1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use. See 6.2, 6.4, 6.5, 6.9, and Section 7.
2. Referenced Documents (purchase separately)
ASTM Standards
D1298 Test Method for Density, Relative Density (Specific Gravity), or API Gravity of Crude Petroleum and Liquid Petroleum Products by Hydrometer Method
D4052 Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter
D5762 Test Method for Nitrogen in Petroleum and Petroleum Products by Boat-Inlet Chemiluminescence
D6299 Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
D4052 Test Method for Density, Relative Density, and API Gravity of Liquids by Digital Density Meter
D5762 Test Method for Nitrogen in Petroleum and Petroleum Products by Boat-Inlet Chemiluminescence
D6299 Practice for Applying Statistical Quality Assurance and Control Charting Techniques to Evaluate Analytical Measurement System Performance
Index Terms
Trace elements--petroleum products; Viscosity--petroleum products; Process feeds; Boundary lubrication properties; Chemiluminescence detection; Combustion--petroleum products; Distillate fuels; Hydrocarbons; Naphtha and naphtha derivatives; Nitrogen content--petroleum products; Petroleum oils;
